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Analytical Instrumentation MCQ Question Set 7
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1. The zero stability of vibrating condenser amplifier type pH meter is much better than a direct coupled amplifier.
True
False
all of the above
None of the mentioned
2. In vibrating condenser amplifier type pH meter, to maintain good performance which of the following has to be done?
Frequency of the vibrator should be stable
Frequency of the vibrator should be constant
Amplitude of the vibrator should be constant
Both frequency and amplitude of the vibrator should be constant and stable
3. If an instrument fails to balance at zero, it is most likely that the electrodes are defective.
True
False
all of the above
None of the mentioned
4. Which of the following is not the characteristic of ion selective electrodes?
It is fragile
Easy to use
Available in different sizes and shapes
It is insensitive to many ions
5. In glass membrane electrode, the glass containing 11% Na2O, 18% Al2O3, 71% SiO2 is highly sensitive to which of the following ions?
Sodium
Hydrogen
Nitrogen
Chlorine
6. In liquid membrane electrode, the liquid ion exchanger is held in a porous disc of _______
Solid material
Semi-permeable membrane
Hydrophobic material
Water absorbing material
7. In recent liquid membrane electrodes, the porous liquid membrane is replaced with which of the following?
Polyvinyl chloride
Polyacryl chloride
Polyester membrane
Polyacryl amide
8. Which of the following is used in potassium electrode in liquid membrane electrodes?
Ionomycin
Valinomycin
Nonactin
Gramicidin
9. In solid state membranes, the body of the electrodes are made of which of the following?
Polyvinyl chloride
Plastic
Polythene
Teflon
10. Ion selective electrode are unaffected by colour or turbidity of the solution.
True
False
all of the above
None of the mentioned
11. Which of the following is not a problem of ion selective electrodes?
Interference with other ions
Output is influences by ionic strength
Drift in electrode potential during a sequence of measurements
Can measure only positive ions
12. Which of the following is the effective concentration measured at the electrode head?
Selectivity coefficient
Ionic strength
Activity
Activity coefficient
13. The value of activity coefficient is always in which of the following ranges?
Zero
Less than zero
Less than 1
Greater than 1
14. Which of the following specifies the relation between ionic strength and activity coefficient?
Directly proportional
Inversely proportional
Equal
No particular relation
15. The difference between measured activity and actual concentration becomes higher at higher concentration. Is this statement true or false?
True
False
all of the above
None of the mentioned
16. Ion selective electrodes have ________ linear range and _________ detection limit than the pH electrode.
Lower, lower
Lower, higher
Lower, higher
Higher, higher
17. In Ammonia electrode, diffusion of dissolved ammonia occurs through the membrane until which of the following conditions occur?
Concentration becomes equal on both sides
Activity becomes equal on both sides
Partial pressure becomes equal on both sides
Differential pressure is low
18. When electrode potential response is plotted as a function of ammonia concentration on a semi-log graph, the graph obtained will be ________
A straight line
Parabolic
Sigmoidal
A curve
19. How can samples above 1M in ammonia concentration be measured using ammonia electrode?
It must be diluted and measured
It cannot be measured
The electrode has to be modified for measuring
It can be measured directly
20. The dilution of solution must not reduce the level of ammonia below _________
10-2 M
10-5 M
10-8 M
10-9 M
21. Which of the following factors does not the reproducibility of the ammonia electrode?
Temperature
Drift
Noise
Dilution
22. The performance of ammonia electrode is not affected by sample colour and turbidity.
True
FALSE
all of the above
None of the mentioned
23. In fluoride ion electrode, the potential corresponding to level of the fluoride ion is described by which of the following equations when E is the measured electrode potential, Eo is the reference potential and A is the level of fluoride ions in solution?
E=Eo+0.0591 log A
E=Eo-0.0591 log A
E=Eo+0.0896 log A
E=Eo-0.0896 log A
24. What does TISAB which is used to overcome interferences stand for?
Total Isolation Strength Absolute Buffer
Total Ionic Strength Absolute Buffer
Total Ionic Strength Adjustment Buffer
Total Isolation Strength Adjustment Buffer
25. Which of the following causes main interference in Fluoride electrode?
H+ ions
OH– ions
Li+ ions
Cl– ions
26. Crystal membrane of ion selective electrode can be regenerated by washing with which of the following?
Alcohol
Iodine solution
Acidic solution
Basic solution
27. For fluoride electrode, the electrode response curve will not only shift but will change slope with changes in temperature.
True
False
all of the above
None of the mentioned
28. Which of the following gas permeable membrane is used for ammonia gas sensing electrode?
Silicon rubber
Microporous Teflon membrane
Fluorocarbon
Polythene
29. Which of the following gas permeable membrane is used for carbon dioxide gas sensing electrode?
Silicon rubber
PVC membrane
Fluorocarbon
Polythene
30. The response time of the biocatalytic membrane electrode is poor when used with complex organic molecules.
True
False
all of the above
None of the mentioned
31. Which of the following reference electrode is placed in the solution of carbon dioxide electrode?
Calomel electrode
Silver/silver chloride electrode
Mercury/mercury sulphate electrode
Glass electrode
32. Biocatalytic membrane electrode cannot be used for the measurement of which of the following gases?
Ammonia
Carbon dioxide
Hydrogen
nitrogen
33. The biocatalytic membrane used in the ammonia selective electrode is which of the following?
Urea
Urease
Acrylamide
Polyacrylamide
34. Which of the following materials are used as a gel to which biocatalytic membrane is fixed in ammonia selective electrode?
Urea
Urease
Acrylamide
Polyacrylamide
35. The biocatalytic membrane is attached to the glass electrode using which of the following materials?
Nylon mesh
Teflon
Silicon rubber
Polythene
36. The response time of the biocatalytic electrode is a function of the thickness of the enzyme layer.
True
False
all of the above
None of the mentioned
37. In carbon dioxide electrode, the membrane separates which of the following?
Sodium carbonate, magnesium chloride
Magnesium hydrogen carbonate, sodium chloride
Sodium hydrogen carbonate, sodium chloride
Magnesium carbonate, magnesium chloride
38. If a solid or liquid membrane is placed in pure water, the membrane dissolves slightly, producing an equilibrium concentration of the measured ion. This is represented as ______
A constant, Eo
Activity
Blank correction, Cb
Concentration of standard solution, Cs
39. During which of the following conditions is the blank correction not necessary?
If sample concentration rises in linear response region
If sample concentration falls in linear response region
If sample concentration rises in non-linear response region
If sample concentration falls in non-linear response region
40. During which of the following conditions is the blank correction necessary?
If sample concentration rises in linear response region
If sample concentration falls in linear response region
If sample concentration rises in non-linear response region
If sample concentration falls in non-linear response region
41. Ion analysers need calibration once in which of the following durations?
Every two or three hours
Every nine or ten hours
Every 24 hours
Every 48 hours
42. In ion analysers, which of the following serve the dual purpose of controlling the operating current of FET and providing current gain?
FET itself does it
SCR
Op-amp
Diode
43. The presence of dirt or moisture degrades which of the following?
Circuit components
High input impedance of buffer amplifier
Low input impedance of buffer amplifier
Low output impedance of buffer amplifier
44. Which of the following is not a type of ground in ion analyser?
Chassis and electrostatic ground
Digital ground
Analog ground
Reference ground
45. The timing for a microprocessor and for all signals is generated by the CPU clock.
True
False
all of the above
None of the mentioned
46. Which of the following is the only operator entry required in PC-based ion analysers?
Hardware set-up
Signal measurement
Calibration
Sample calculation
47. The analog and digital grounds are connected together in ion analysers.
True
False
all of the above
None of the mentioned
48. Which of the following is not a characteristic of the immobilized enzymes?
They cannot be re-used
It produces reproducible results
Stability exists
Same catalytic activity is present for number of analysis
49. Which of the following is the physico-chemical component?
Enzymes
Anti-bodies
Transducer
Cells or tissues
50. An example of biosensor, urea electrode makes use of which of the following electrodes?
Carbon dioxide electrode
Ammonia electrode
Fluoride electrode
Ammonium electrode
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